Degradation of Methylene Blue Using Microplasma Discharge – A Relative Study with Photodegradation

  • Gopika K.P Surface & Environmental Control Plasma Lab, Department of Physics, Bharathiar University, Coimbatore–641046, India
  • Kavitha E.R Surface & Environmental Control Plasma Lab, Department of Physics, Bharathiar University, Coimbatore–641046, India
  • Meiyazhagan S Surface & Environmental Control Plasma Lab, Department of Physics, Bharathiar University, Coimbatore–641046, India
  • Nitin Jasper Paul Surface & Environmental Control Plasma Lab, Department of Physics, Bharathiar University, Coimbatore–641046, India
  • Suresh K Surface & Environmental Control Plasma Lab, Department of Physics, Bharathiar University, Coimbatore–641046, India
Keywords: Non-thermal Plasma, Microplasma, Methylene Blue, Dye Degradation, Photodegradation

Abstract

Large-scale production and application of synthetic dyes have become a matter of concern as it is a major factor responsible for environmental pollution. Most dyeing effluents are discharged into water bodies and lands without being treated, which ultimately pollutes the groundwater making it unfit for consumption. The present study explains the degradation of one of such synthetic dyes Methylene blue (MB), using non-thermal Microplasma treatment. The aqueous solution of MB was treated with an array of air microplasma discharge at atmospheric pressure. Different concentrations (10 ppm, 20 ppm) of MB solution were treated for various treatment time and chemical parameters like pH, electrical conductivity, total dissolved solids and salinity was measured. The degradation percentage reached 100% in 15 min of treatment for 10 ppm MB solution, and 20 min of treatment for 20 ppm MB solution indicated by the color change from blue to a clear solution. The reactive oxygen species (ROS) and reactive nitrogen species (RNS) formed during the microplasma treatment are responsible for MB degradation. Same volume of MB solution was irradiated by direct sunlight for photodegradation and was found to degrade the solution of 10 ppm by 96% and 20 ppm by 93% in 10 hours of treatment. Experimental results indicated that microplasma treatment was effective for dye degradation, without the need for pretreatment process or chemicals.

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References

Asghar, M.M. Bello, Raman, A.A.A. Daud, W.M.A.W. Daud, A. Ramalingam, S.B.M. Zain, Predicting the Degradation Potential of Acid Blue 113 by Different Oxidants using Quantum Chemical Analysis, Heliyon, 5 (2019) e02396. https://doi.org/10.1016/j.heliyon.2019.e02396

P.V. Nidheesh, M. Zhou, M. A. Oturan, An Overview on the Removal of Synthetic Dyes from Water by Electrochemical Advanced Oxidation Processes, Chemosphere, 197 (2018) 210-227. https://doi.org/10.1016/j.chemosphere.2017.12.195

I. Ihsanullah, A. Jamal, M. Ilyas, M. Zubair, G. Khan, M. A. Atieh, Bioremediation of Dyes: Current Status and Prospects, Journal of Water Process Engineering, 38 (2020) 101680. https://doi.org/10.1016/j.jwpe.2020.101680

B. Lellis, C.Z. Fávaro-Polonio, J.A. Pamphile, J.C. Polonio, Effects of Textile Dyes on Health and the Environment and Bioremediation Potential of Living Organisms, Biotechnology Research and Innovation 3 (2019) 275-290. https://doi.org/10.1016/j.biori.2019.09.001

M.T. Yagub, T.K. Sen, S. Afroze, H.M. Ang, Dye and its Removal from Aqueous Solution by Adsorption: A Review, Advances in Colloid and Interface Science, 209 (2014) 172–184.https://doi.org/10.1016/j.cis.2014.04.002

L. Lin, Q. Wang, Microplasma: A New Generation of Technology for Functional Nanomaterial Synthesis, Plasma Chemistry and Plasma Processing, 35 (2015) 925–962. https://doi.org/10.1007/s11090-015-9640-y

L. Chandana, P.M.K. Reddy, Ch. Subrahmanyam, Atmospheric Pressure Non-thermal Plasma Jet for the Degradation of Methylene Blue in Aqueous Medium, Chemical Engineering Journal, 282 (2015) 116-122. https://doi.org/10.1016/j.cej.2015.02.027

M.C García, M. Mora, D. Esquivel, J.E. Foster, A. Rodero, C. Jiménez- Sanchidrián, F.J. Romero-Salguero, Microwave Atmospheric Pressure Plasma Jets for Wastewater Treatment: Degradation of Methylene Blue as a Model Dye, Chemosphere 180 (2017), 239-246. http://dx.doi.org/10.1016/j.chemosphere.2017.03.126

M. Magureanu, D. Piroi, N.B. Mandache, V. Parvulescu, Decomposition of Methylene Blue in Water using a Dielectric Barrier Discharge: Optimization of the Operating Parameters, Journal of Applied Physics, 104 (2008) 103306. https://doi.org/10.1063/1.3021452

P. M. K. Reddy, B. R. Raju, J. Karuppiah, E. L. Reddy, Ch. Subrahmanyam, Degradation and Mineralization of Methylene Blue by Dielectric Barrier Discharge Non-Thermal Plasma Reactor, Chemical Engineering Journal 217 (2013) 41–47.https://doi.org/10.1016/j.cej.2012.11.116

S. Meiyazhagan, S. Yugeswaran, P.V. Ananthapadmanabhan, K. Suresh, Proximative and Contrastive Study of Malachite Green Dye Degradation Using Microplasma Discharge With Postliminary Phytotoxicity Analysis, IEEE Transactions On Plasma Science, 49 (2021) 597-603. https://doi.org/10.1109/TPS.2020.3005427

S. Meiyazhagan, S. Yugeswaran, P.V. Ananthapadmanabhan, K. Suresh, Process and Kinetics of Dye Degradation using Microplasma and its Feasibility in Textile Effluent Detoxification, Journal of Water Process Engineering, 37 (2020) 101519. https://doi.org/10.1016/j.jwpe.2020.101519

F. Huang, L. Chen, H. Wang, Z. Yan, Analysis of the Degradation Mechanism of Methylene Blue by Atmospheric Pressure Dielectric Barrier Discharge Plasma, Chemical Engineering Journal, 162 (2010) 250–256. https://doi.org/10.1016/j.cej.2010.05.041

L. Wu, Q. Xie, Y. Lv, Z. Wu, X. Liang, M. Lu, Y. Nie, Degradation of Methylene Blue via Dielectric Barrier Discharge Plasma Treatment, Water, 11 (2019) 1818. http://dx.doi.org/10.3390/w11091818

T. Soltani, M.H. Entezari, Photolysis and Photocatalysis of Methylene Blue by Ferrite Bismuth Nanoparticles under Sunlight Irradiation, Journal of Molecular Catalysis A: Chemical, 377 (2013) 197– 203. https://doi.org/10.1016/j.molcata.2013.05.004

S. Meiyazhagan, S. Yugeswaran, P. V. Ananthapadmanabhan, P. R. Sreedevi, K. Suresh, Relative Potential of Different Plasma Forming Gases in Degradation of Rhodamine B Dye by Microplasma Treatment and Evaluation of Reuse Prospectus for Treated Water as Liquid Fertilizer, Plasma Chemistry and Plasma Processing, 40 (2020) 1267–1290.

Published
2021-05-23
How to Cite
K.P, G., E.R, K., S, M., Paul, N. J., & K, S. (2021). Degradation of Methylene Blue Using Microplasma Discharge – A Relative Study with Photodegradation. Frontiers in Advanced Materials Research, 3(1), 26-35. https://doi.org/10.34256/famr2113
Section
Articles



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